Mono-and bis(5-O-nitro-1,4:3,6-dianhydro-D-sorbit-2-yl) phosphates: synthesis and reactions with hydroxy-and amino-containing compounds

Autor:	G. V. Oreshko, G. G. Aleksandrov, L. T. Eremenko, G. V. Lagodzinskaya, Igor L. Eremenko
Rok vydání:	2007
Předmět:	chemistry.chemical_compound Hydrolysis Organic base Chemistry Sodium Nitro Organic chemistry chemistry.chemical_element Phenol General Chemistry Pentaerythritol Phosphoric acid
Zdroj:	Russian Chemical Bulletin. 56:2097-2104
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-007-0327-2
Popis:	The reaction of 1,4:3,6-dianhydro-D-sorbitol 5-nitrate with POCl3 afforded mono-and bis(5-O-nitro-1,4:3,6-dianhydro-D-sorbit-2-yl) phosphorochloridates, whose hydrolysis resulted in phosphoric acid mono-and diesters. The subsequent treatment of these compounds with bases gave sodium and cyclohexylammonium salts. The reactions of phosphorochloridates with phenol, pentaerythritol dibromohydrin, and ethylenimine in the presence of organic bases afford mixed phosphates and phosphoramidates.
Databáze:	OpenAIRE
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