Bis(μ-propan-2-olato-κ2O:O)bis[chlorido(propan-2-ol-κO)bis(propan-1-olato-κO)tin(IV)]

Autor:	Eduard B. Rusanov, Nikolai Klishin, Anatoliy I. Brusilovets, Oleksii Brusylovets
Rok vydání:	2012
Předmět:	Octahedron Hydrogen bond Chemistry SN2 reaction General Materials Science General Chemistry Condensed Matter Physics Medicinal chemistry
Zdroj:	Acta Crystallographica Section E Structure Reports Online. 68:m337-m338
ISSN:	1600-5368
DOI:	10.1107/s1600536812007799
Popis:	The binuclear centrosymmetric title compound, [Sn2(C3H7O)6Cl2(C3H8O)2], exhibits an edge-shared double octahedral exhibits an edge-shared octa­hedral structure, which is distorted owing to the presence of asymmetric intra­molecular hydrogen bonds between the axially coordinated isopropanol and isopropoxide ligands. The H atom of the hy­droxy group is located nearer to an isoprop­oxy group with the longest Sn—O bond [2.1789 (17) A].
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4d196e63d4d9a44cac423b255b85dd38 https://doi.org/10.1107/s1600536812007799 Zobrazit plný text záznamu