The alkoxy–alkoxycarbonylation of allenes

Autor:	Bertrand Despeyroux, Howard Alper, Frederick W. Hartstock
Rok vydání:	1984
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Hydrocarbon Chemistry Allene Carboxylic acid Yield (chemistry) Alkoxy group Molecular Medicine Organic chemistry Methanol Aliphatic compound Carbon monoxide
Zdroj:	J. Chem. Soc., Chem. Commun.. :905-906
ISSN:	0022-4936
DOI:	10.1039/c39840000905
Popis:	Allene undergoes alkoxy–alkoxycarbonylation under exceedingly mild conditions (CO–O2–MeOH–PdCl2–CuCl2, 0 °C, 1 atm) affording methyl 2-methoxymethylacrylate in good yield; in the case of 1,1-disubstituted allenes the reaction is regiospecific although the product yields are lower.
Databáze:	OpenAIRE
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