Isotope effects in the chlorination of naphthalene
Autor: | P. B. D. de la Mare, J. S. Lomas |
---|---|
Rok vydání: | 2010 |
Předmět: | |
Zdroj: | Recueil des Travaux Chimiques des Pays-Bas. 86:1082-1088 |
ISSN: | 0165-0513 |
Popis: | The chlorination of naphthalene shows an inverse deuterium isotope effect, the reaction of naphthalene being slower than that of octadeuterionaphthalene by a factor of 0.85. The product-forming stages are also subject to a deuterium isotope effect which influences the partitioning between addition and substitution; the most direct interpretation of the results is that the values of kH/kD for the stages of proton-loss are subject to a normal deuterium isotope effect, with kH/kD ⦔ 1.4. |
Databáze: | OpenAIRE |
Externí odkaz: |