Isotope effects in the chlorination of naphthalene

Autor:	P. B. D. de la Mare, J. S. Lomas
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Deuterium Chemistry Inorganic chemistry Kinetic isotope effect lipids (amino acids peptides and proteins) General Chemistry Naphthalene
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas. 86:1082-1088
ISSN:	0165-0513
Popis:	The chlorination of naphthalene shows an inverse deuterium isotope effect, the reaction of naphthalene being slower than that of octadeuterionaphthalene by a factor of 0.85. The product-forming stages are also subject to a deuterium isotope effect which influences the partitioning between addition and substitution; the most direct interpretation of the results is that the values of kH/kD for the stages of proton-loss are subject to a normal deuterium isotope effect, with kH/kD ⦔ 1.4.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4cdd39fdc3301402de02ba999e78ad97 https://doi.org/10.1002/recl.19670861009 Zobrazit plný text záznamu