Interaction of Comblike Polymethacrylates with N-Octacosane

Autor:	Rocco D. Pugliese, Isaac D. Rubin
Rok vydání:	1991
Předmět:	chemistry.chemical_classification Materials science General Engineering Polymer Methacrylate law.invention Crystallinity Differential scanning calorimetry Chemical engineering chemistry law Phase (matter) Polymer chemistry Copolymer Orthorhombic crystal system Crystallization
Zdroj:	Journal of Macromolecular Science: Part A - Chemistry. 28:111-119
ISSN:	0022-233X
DOI:	10.1080/00222339108054391
Popis:	The nature of polymethacrylate (PMA) interactions with n-octacosane (n-C28) was probed using differential scanning calorimetry and powder X-ray diffraction. Blends containing comblike homopolymer and copolymer methacrylates were chosen to investigate the role of polymer side-chain crystallinity upon the crystallization behavior of n-C as a model n-paraffin compound. All PMAs disrupted the platelet morphology of the n-C28 while enhancing development of crystal planes along the n-paraffin chain axis. In addition, evidence supporting both orthorhombic phase stabilization and cocrystallization is reported for one solidified melt containing poly(n-octadecyl methacrylate).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4cc49ba8ed23d447a43ae0d66d7b4ec7 https://doi.org/10.1080/00222339108054391 Zobrazit plný text záznamu