Decatungstate as a direct hydrogen atom transfer photocatalyst for synthesis of trifluromethylthioesters from aldehydes

Autor:	Qingmin Wang, Yuxiu Liu, Hongjian Song, Jianyang Dong, Xiaochen Wang
Rok vydání:	2021
Předmět:	Chemistry Bioactive molecules Photocatalysis Surface modification General Chemistry Hydrogen atom Highly selective Combinatorial chemistry Catalysis
Zdroj:	Chinese Chemical Letters. 32:3027-3030
ISSN:	1001-8417
DOI:	10.1016/j.cclet.2021.03.070
Popis:	We have developed a versatile, mild protocol for trifluoromethylthiolation reactions of aldehydes with catalysis by a decatungstate hydrogen atom transfer photocatalyst under redox-neutral conditions. The protocol is highly selective, operationally simple, and compatible with a wide array of sensitive functional groups. It can be used for late-stage functionalization of bioactive molecules, which makes it convenient for drug discovery.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4ca57dd27ce6284c43021d8d81b0cf39 https://doi.org/10.1016/j.cclet.2021.03.070 Zobrazit plný text záznamu Full Text from ScienceDirect