Reaction of stereoisomeric bis(cyclohexyl)-2,2?-diones with hydrogen peroxide: structure of the formed adducts

Autor:	Sergey Lindeman, E. K. Starostin, A. V. Ignatenko, Yu. T. Struchkov, Victor N. Khrustalev, Gennady I. Nikishin
Rok vydání:	1995
Předmět:	chemistry.chemical_compound chemistry Organic chemistry General Chemistry Methanol Nuclear magnetic resonance spectroscopy Hydrogen peroxide Medicinal chemistry Adduct Tetradecane
Zdroj:	Russian Chemical Bulletin. 44:907-912
ISSN:	1573-9171 1066-5285
DOI:	10.1007/bf00696925
Popis:	The reaction ofmeso- andD,L-forms of bis(cyclohexyl)-2,2′-dione with a methanol solution of hydrogen peroxide in a neutral medium has been studied. It has been established that in the case of theD,L-formrac-(1R,4R,9S,10S)-1,4-dihydroxy-2,3-dioxatricyclo-[8.4.0.04,9] tetradecane is formed, while themeso-form affordsrac-(1R,4R,9S,10R)-1-methoxy-4-hydroxy-2, 3-dioxatricyclo[8.4.0.04,9]tetradecane. The structures of the compounds have been established by X-ray structural analysis and by1H and13C NMR spectroscopy.
Databáze:	OpenAIRE
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