N-Methoxyamide: An Alternative Amidation Reagent in the Rhodium(III)-Catalyzed C–H Activation
| Autor: | Ji-Jun Jiang, Chao Zhou, Junqi Zhao, Jun Wang, Weicong Guo |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
010405 organic chemistry
Organic Chemistry chemistry.chemical_element Substrate (chemistry) 010402 general chemistry 01 natural sciences Biochemistry Medicinal chemistry 0104 chemical sciences Catalysis Rhodium Boric acid chemistry.chemical_compound chemistry Reagent Physical and Theoretical Chemistry |
| Zdroj: | Organic Letters. 21:9315-9319 |
| ISSN: | 1523-7052 1523-7060 |
| DOI: | 10.1021/acs.orglett.9b03357 |
| Popis: | In the field of transition-metal-catalyzed C-H activation, N-methoxyamides are widely used as C-H activation substrate. Unexpectedly, in this work N-methoxyamides were found to work as efficient amidation reagents in the rhodium(III)-catalyzed C-H activation with boric acid as a cocatalyst. This reaction features broad substrate scope and good yields. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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