Polymerization of cycloolefins in the presence of catalysts containing tungsten halides and allylsilanes

Autor:	I. A. Oreshkin, I. L. Kershenbaum, G.M. Chernenko, E. I. Tinyakova, K. L. Makovetskii, L. I. Red'kina, B. A. Dolgoplosk
Rok vydání:	1977
Předmět:	chemistry.chemical_compound Chain-growth polymerization chemistry Polymerization Allyl compound chemistry.chemical_element Cyclopentene Chain transfer General Chemistry Tungsten Ionic polymerization Photochemistry Catalysis
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:2377-2381
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00958731
Popis:	1. Allyl compounds of silicon in combination with tungsten halides effectively catalyze the ring-opening polymerization of cycloolefins. 2. Polymerization of cyclopentene by the catalyst system WCl6-tetraallylsilane between -20 and -78°C forms a polypentenamer with 94–99% cis-units. 3. We have studied the polymer-monomer equilibrium in the cis-polymerization of cyclopentene by the WC16- tetraallylsilane system and have determined some thermodynamic parameters for the process.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4c76e205fc2aa3700aca587decb70859 https://doi.org/10.1007/bf00958731 Zobrazit plný text záznamu Full text from SpringerLink