Highly Active Ammonium-Tagged Olefin-Metathesis Catalyst for Simplified Purification

Autor:	Karol Grela, Klaas Mennecke, Axel Meyer, Łukasz Gułajski, Torsten Busch, Andreas Kirschning
Rok vydání:	2008
Předmět:	Chemistry Ligand Organic Chemistry Ruthenium catalyst Metathesis Enyne metathesis Catalysis law.invention chemistry.chemical_compound law Organic chemistry Ring-opening metathesis polymerisation Ammonium Filtration
Zdroj:	Synlett. 2008:2692-2696
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0028-1083512
Popis:	When an 2-isopropoxy-substituted benzylidene ligand of a Hoveyda-type Ru-metathesis complex is modified by an additional 4-diethylamino group and treated wit PTSA it yields a highly active precatalyst suitable for RCM, cross metathesis, and enyne metathesis. The important property of this ammonium tagged Ru-complex is associated with the possibility of its easy removal by a simple filtration protocol.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4c67a119e99c7c0afeb826e229600987 https://doi.org/10.1055/s-0028-1083512 Zobrazit plný text záznamu