Surface enhanced raman spectroscopy of cyanide complexes on silver surfaces

Autor: Gabriel Laufer, James T. Huneke, Theodore F. Schaaf
Rok vydání: 1981
Předmět:
Zdroj: Chemical Physics Letters. 82:571-576
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85443-7
Popis: Silver samples electrochemically treated with cyanide exhibit surface enhanced Raman spectra of silver cyanide complexes when examined in air. Surface enhancement is observed from [Ag(CN) 3 ] 2− before rinsing and [Ag(CN) 3 ] − after rinsing. A bulk overlayer of [Ag(CN) 2 ] − is removed by the rinse. All lines are red-shifted when Na + counter ions are replaced by K + .
Databáze: OpenAIRE