| Autor: |
James E. Matt, Paul A. Grieco, Kenneth J. Henry, Joseph J. Nunes |
| Rok vydání: |
1992 |
| Předmět: |
|
| Zdroj: |
J. Chem. Soc., Chem. Commun.. :368-370 |
| ISSN: |
0022-4936 |
| Popis: |
The total synthesis of sesbanimide A (1) and B (2) is reported which features (a) the reaction of cyclopentadiene with glyoxylic acid leading to the useful bicyclic lactone building block 3 and (b) the use of 2.5 mol dm–3 lithium perchlorate in diethyl ether to promote the conjugate addition of 1-methoxy-1-(tert-butyldimethylsiloxy)ethene to unsaturated lactone 11. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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