Fused multifunctionalized bridge aromatic hydrocarbons from in situ-generated arynes and anthracene derivatives

Autor: Qiong Hu, Feihu Yang, Xiaojie Zheng, Yimin Hu, Baohua Liu
Rok vydání: 2020
Předmět:
Zdroj: Chinese Chemical Letters. 31:1305-1308
ISSN: 1001-8417
Popis: This study presents a facile strategy for the formation of highly substituted butterfly 1,4-adducts/9,10-adducts via the Diels–Alder reaction of benzyne intermediates. The method achieves very good to excellent yields of the respective anthracene derivatives under mild conditions. This practical protocol is compatible with a variety of sensitive functional groups and provides access to difunctionalized bridge 1,4-adducts/9,10-adducts.
Databáze: OpenAIRE