Solvothermally derived Me2(H2O)4(5SSA)3·DMF and Me2(H2O)4(4NSA)2·DMF: Application as Biginelli reaction catalysts

Autor:	Izzet Amour Morkan, Robertas Žilinskas, Fatma Yalçin, Albinas Žilinskas, Andrius Laurikėnas, Aivaras Kareiva, Ayse Uztetik Morkan
Rok vydání:	2019
Předmět:	Chemistry Biginelli reaction General Chemistry Combinatorial chemistry Catalysis
Zdroj:	Chemija. 30
ISSN:	2424-4538 0235-7216
Popis:	The solvothermal synthesis between Me(NO3)x ∙ yH2O (Mex+ = Fe3+, Ni2+, Mn2+, Co2+, Cu2+) and respectively 4-nitrosalycilic (4NSA) and 5-sulfosalicylic (5SSA) acids produced hybrid organic-inorganic compounds composed of Mex+ ions and organic fragments which include three different functional groups, carboxylic, hydroxyl and sulfonic, each coordinated to the Mex+ ions. The phase and chemical composition, microstructure and properties of Me2(H2O)4(5SSA)3·DMF and Me2(H2O)4(4NSA)2·DMF (DMF – dimethylformamide) hybrid compounds were evaluated and discussed. The synthesised materials were characterised by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM) and nuclear magnetic resonance (NMR) spectroscopy. The catalytic properties of the obtained compounds were also investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4c351f1ae9b31f1641db20408be0b86a https://doi.org/10.6001/chemija.v30i2.3998 Zobrazit plný text záznamu