Incorporation of g-C3N4/Ag dopant in TiO2 as electron transport layer for organic solar cells
Autor: | Mohamad Firdaus Mohamad Noh, Chi Chin Yap, Nurul Nazli Rosli, Eng Liang Lim, Mohd Asri Mat Teridi, Mohd Fairuz Soh, Javad Safaei, Nurul Aida Mohamed |
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Rok vydání: | 2019 |
Předmět: |
Photocurrent
Nanocomposite Materials science Dopant Organic solar cell Mechanical Engineering Energy conversion efficiency Oxide Graphitic carbon nitride chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences chemistry.chemical_compound chemistry Chemical engineering Mechanics of Materials General Materials Science 0210 nano-technology Titanium |
Zdroj: | Materials Letters. 253:117-120 |
ISSN: | 0167-577X |
DOI: | 10.1016/j.matlet.2019.06.052 |
Popis: | Graphitic carbon nitride (g-C3N4) and silver (Ag) co-modified titanium (IV) oxide (TiO2) was developed and employed as electron transport layer (ETL) in organic solar cell (OSC) to improve electron extraction and transport. The morphological, optical and electrical properties of the ETL were investigated using X-ray diffraction, atomic force microscopy and photocurrent density-voltage measurement. The OSC exhibited maximum power conversion efficiency of 1.7% which is 30% and 13% higher than devices based on pristine TiO2 and g-C3N4/TiO2 nanocomposite, respectively. The enhancement of OSC performance was primarily ascribed to (1) smoother surface of ETL ensuring good interfacial adhesion between ETL and polymer layer, (2) enhanced light scattering effect and (3) effective electron collection and suppressed recombination at ETL/polymer interface. |
Databáze: | OpenAIRE |
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