ChemInform Abstract: Differentially Protected Benzenediboronic Acids: Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes

Autor:	Takayuki Shioda, Chih-Ming Chou, Hiroyoshi Noguchi, Michinori Suginome
Rok vydání:	2008
Předmět:	inorganic chemicals Coupling (electronics) chemistry.chemical_classification Chemistry chemistry.chemical_element General Medicine Boron Highly selective Combinatorial chemistry Divalent
Zdroj:	ChemInform. 39
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200827174
Popis:	On the basis of the boron-masking strategy, new divalent cross-coupling modules have been designed for the efficient synthesis of boron-substituted oligoarenes. The modules, i.e., monoprotected o-, m-, and p-benzenediboronic acid derivatives, undergo highly selective Suzuki−Miyaura coupling with sp2 iodides, bromides, chlorides, and triflates, affording coupling products in which the protected boronyl groups are left intact.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4c04d750ee063e729ca75975efbad8d1 https://doi.org/10.1002/chin.200827174 Zobrazit plný text záznamu Plný text