Influence of Sequential Nitrogen Substitution on the Redox Properties of Bis(thiazolylidene)hydrazine and on the Charge Transfer of TCNQ Complexes
| Autor: | Dominique Lorcy, David Guérin, L. Piekara-Sady, Roger Carlier, Szymon Los |
|---|---|
| Rok vydání: | 2002 |
| Předmět: |
Nitrile
Hydrazine Inorganic chemistry chemistry.chemical_element Crystal structure Condensed Matter Physics Nitrogen Redox Magnetic susceptibility Electronic Optical and Magnetic Materials Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Materials Chemistry Ceramics and Composites Molecule Physical and Theoretical Chemistry Thiazole |
| Zdroj: | Journal of Solid State Chemistry. 168:590-596 |
| ISSN: | 0022-4596 |
| Popis: | Various extended π-donor molecules incorporating an azino spacer between two heterocyclic moieties, either dithiole or thiazole rings, are described. As evidenced by cyclic voltammetric studies, the donor ability of these derivatives can be modulated depending on the nature of the two heterocycles. Three similar crystalline complexes were obtained with TCNQ and the donors 4, 7 and 8. Crystal structures and magnetic susceptibility data of these complexes are presented and the degree of charge transfer within these complexes has been correlated with the redox properties. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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