A new zinc coordination polymer constructed from 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid: synthesis, structure, and photoelectrical property
| Autor: | Zhi-Chen Liu, Li-Ying Yu, Xiao-Yang Yu, Ya-Nan Luo, Hui-Ying Jiang |
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| Rok vydání: | 2018 |
| Předmět: |
Tandem
010405 organic chemistry Coordination polymer Supramolecular chemistry chemistry.chemical_element Zinc 010402 general chemistry Condensed Matter Physics 01 natural sciences Hydrothermal circulation 0104 chemical sciences law.invention chemistry.chemical_compound Benzenesulfonic acid chemistry law Solar cell Polymer chemistry Irradiation Physical and Theoretical Chemistry |
| Zdroj: | Structural Chemistry. 29:977-982 |
| ISSN: | 1572-9001 1040-0400 |
| DOI: | 10.1007/s11224-018-1079-3 |
| Popis: | One new supramolecular compound based on H2L (H2L = 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid, C15H11O4N3S), [Zn3L2(OH)2(H2O)6]n (1), has been synthesized by hydrothermal technique. Compound 1 exhibits a one-dimensional (1-D) double-chain structure. Compound 1 is the first example of an azo complex used to co-sensitize TiO2 photoanode with Ru dyes (N719, N3). In the tandem structure of compound 1/N719/TiO2, compound 1 plays a significant role in the improvement of the photoelectric conversion efficiency, which works with N719 to modify the energy level. The results show that the compound 1/N719/TiO2 solar cell exhibited excellent photovoltaic performance with the photoelectric conversion efficiency of 7.1% under standard global AM 1.5 solar irradiation conditions. |
| Databáze: | OpenAIRE |
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