Quantum capture of charged particles by rapidly rotating symmetric top molecules with small dipole moments: analytical comparison of the fly-wheel and adiabatic channel limits

Autor:	J. Troe, Marcis Auzinsh, E. I. Dashevskaya, E. E. Nikitin
Rok vydání:	2013
Předmět:	Coupling Physics Angular momentum Range (particle radiation) Biophysics Condensed Matter Physics Charged particle Dipole Moment (physics) Physical and Theoretical Chemistry Atomic physics Adiabatic process Molecular Biology Quantum
Zdroj:	Molecular Physics. 111:2003-2011
ISSN:	1362-3028 0026-8976
Popis:	The rate coefficients for capture of charged particles by spherical top molecules, which by isotopic substitution become symmetric top molecules with small dipole moment, are expressed analytically for the two limiting cases of weak coupling of the molecular angular momentum to the collision axis (dominating Coriolis interaction, the fly-wheel [FW] approximation) and strong coupling (negligible Coriolis interaction, the adiabatic channel [AC] approximation). The comparison leads to relations between rate coefficients for ultra-low (FW) and moderate (AC) temperatures and defines the range of parameters for which the analytical expressions become insufficient and a numerical treatment is necessary.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4be4cbc0619a6376b5405bc6d3028e0c https://doi.org/10.1080/00268976.2013.780101 Zobrazit plný text záznamu