A Novel Coordinated Polymer [Cu(En)2][(PzTp)Fe(CN)3]2: Synthesis, Crystal Structure, and Inhibiting Left Atrial Myxoma Cell Activity in vitro
| Autor: | D. K. Chen, X. L. Zhou, Chenglv Hong, F. He, F. Q. Dong |
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| Rok vydání: | 2018 |
| Předmět: |
biology
010405 organic chemistry General Chemical Engineering chemistry.chemical_element Ethylenediamine General Chemistry Crystal structure 010402 general chemistry biology.organism_classification 01 natural sciences 0104 chemical sciences Solvent chemistry.chemical_compound Crystallography chemistry Octahedron Tetra Molecule Boron Single crystal |
| Zdroj: | Russian Journal of Coordination Chemistry. 44:179-182 |
| ISSN: | 1608-3318 1070-3284 |
| DOI: | 10.1134/s1070328418030089 |
| Popis: | A new cyanide-bridged neutral centrosymmetric cluster [Cu(En)2][(PzTp)Fe(CN)3]2 (I), where En = ethylenediamine, PzTp = tetra(pyrazol-1-yl)borate) was synthesized by a programmed self-assembly of preformed building blocks. Characterization with single crystal X-ray diffraction (CIF file CCDC no. 1555334) showed that the Cu2+ center was located in a large distorted octahedral environment due to the obvious Jahn–Teller effect, which was demonstrated by continuous shape measures with the SHAPE program. Furthermore, no coordinated or free solvent molecules existed in the clusters, showing good roomtemperature stability. In addition, in vitro anticancer activity of compound I on three human cancer cells (SKOV3, A2780, and OVCAR) was further determined. |
| Databáze: | OpenAIRE |
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