Radiation generation of exciplexes in triethylamine-ethanol mixtures

Autor: M. Szadkowska-Nicze, J. Piekarska-GoŁȩbiowska, Cz. Stradowski
Rok vydání: 1990
Předmět:
Zdroj: International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry. 36:219-222
ISSN: 1359-0197
DOI: 10.1016/1359-0197(90)90246-e
Popis: Emission of light following pulse and steady-state irradiation of the mixtures of triethylamine-ethanol was studied at 77–180K. The spectra and lifetimes of emitting species were determined. It is suggested that exciplexes of triethylamine-ethanol are responsible for light emission. Various emission bands were compared with that obtained by photoexcitation and assigned to exciplexes of various associates of triethylamine-ethanol. It is postulated that exciplexes observed in pulse radiolysis experiment are formed via recombination of dry electron with the cation while in γ-radiolysis experiment the trapped electron is a precursor of exciplexes.
Databáze: OpenAIRE