Reduction of pyracylene by alkali metals: Mechanism and formation of aggregates
Autor: | Mordecal Rabinovitz, Jakob Wirz, Ari Ayalon, Vladimir Rozenshtein, Gil Zilber, Gaby Persy, Lawrence T. Scott, Haim Levanon, Hope B. Warren |
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Rok vydání: | 1996 |
Předmět: | |
Zdroj: | Research on Chemical Intermediates. 22:839-854 |
ISSN: | 1568-5675 0922-6168 |
DOI: | 10.1163/156856796x00511 |
Popis: | Five reaction stages have been identified in the reduction of pyracylene to its dianion. The same stages were also observed in the photochemical oxidation starting with the dianion. The formation of dimers of anions and of mixed valence aggregates is discussed. |
Databáze: | OpenAIRE |
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