Selective reduction of saturated perfluorocarbons

Autor:	Anne M. Coughlin, John Anthony Marsella, Andrew G. Gilicinski, Guido Peter Pez
Rok vydání:	1992
Předmět:	chemistry.chemical_compound Perfluorocyclohexane chemistry Sodium Organic Chemistry Benzophenone chemistry.chemical_element Selective reduction Photochemistry Carbon Ion
Zdroj:	The Journal of Organic Chemistry. 57:2856-2860
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo00036a019
Popis:	Perfluorocycloaliphatic compounds are reduced by solutions of the sodium benzophenone radical anion to give perfluorinated and highly fluorinated aromatic compounds. Perfluorocycloalkanes containing tertiary carbon centers are much more reactive than perfluorocyclohexane. Reduction of perfluoroalkanes and perfluorocycloalkanes that contain perfluoroalkyl substituents proceeds easily; however, it appears that overreduction occurs and no organofluorine products are obtained with these substrates
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4bba7d1c35ed4522c9c4f0b0fdb2ca6a https://doi.org/10.1021/jo00036a019 Zobrazit plný text záznamu