The thermodynamic properties of 2-ethylhexyl acrylate over the temperature range from T → 0 to 350 K

Autor:	Alla E. Mochalova, N.N. Smirnova, Ya. S. Samosudova, L. A. Smirnova, I. A. Letyanina, T. G. Kulagina, E. V. Sevast’yanov
Rok vydání:	2012
Předmět:	Acrylate chemistry.chemical_compound Devitrification chemistry Analytical chemistry Thermodynamics Physical and Theoretical Chemistry Atmospheric temperature range Adiabatic process 2-ethylhexyl acrylate Combustion Heat capacity Calorimeter
Zdroj:	Russian Journal of Physical Chemistry A. 86:747-751
ISSN:	1531-863X 0036-0244
DOI:	10.1134/s0036024412050172
Popis:	The temperature dependence of the heat capacity C o = f(T) 2 of 2-ethylhexyl acrylate was studied in an adiabatic vacuum calorimeter over the temperature range 6–350 K. Measurement errors were mainly of 0.2%. Glass formation and vitreous state parameters were determined. An isothermic shell calorimeter with a static bomb was used to measure the energy of combustion of 2-ethylhexyl acrylate. The experimental data were used to calculate the standard thermodynamic functions C o (T), H o(T)-H o(0), S o(T)-S o(0), and G o(T)-H o(0) of the compound in the vitreous and liquid states over the temperature range from T → 0 to 350 K, the standard enthalpies of combustion Δc H o, and the thermodynamic characteristics of formation Δf H o, Δf S o, and Δf G o at 298.15 K and p = 0.1 MPa.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4b951090fa81ceca1d5b8cc72dbba455 https://doi.org/10.1134/s0036024412050172 Zobrazit plný text záznamu Full text from SpringerLink