Synthesis and Spectroscopic Studies of Dicarbonylnitrosyl (η3-Allyl) Iron Complexes

Autor:	Muhammad Imran, Zaid Mehmood, Syeda Robina Gillani, Misbah Tabassam
Rok vydání:	2011
Předmět:	Inorganic Chemistry Infrared Chemistry Decarbonylation Physical and Theoretical Chemistry Photochemistry Medicinal chemistry
Zdroj:	Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 41:805-813
ISSN:	1553-3182 1553-3174
Popis:	Some novel complexes (1–9) of [(η3-allyl) Fe(CO)2(NO)] were synthesized by the reaction of tetrabutylammonium ferrate (TBAFe) with different allyl substrates like substituted allyl chlorides, allyl bromides, etc. All the synthesized complexes were characterized on the basis of infrared (IR), nuclear magnetic resonance (1H-NMR and 13C-NMR), and mass spectroscopic data. The spectroscopic data revealed that decarbonylation occurred in each case. It has also been observed that the cleavage of one CO ligand is more facile when more electron donating substituents are located at the allyl ligand. This tendency goes to an extreme in case of the 1,3-dimethylallyl Fe-complex (9).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4b859d8ad62e71403cd2d27298985dfe https://doi.org/10.1080/15533174.2011.591307 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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