The Effect of Thermal Treatment on the Physical Properties of LiCoO2 Stoichiometric Composition

Autor:	R. I. Korneikov, K. A. Kesarev, V. I. Ivanenko, V. V. Efremov
Rok vydání:	2021
Předmět:	Materials science chemistry.chemical_element Ionic bonding Thermal treatment Conductivity Thermal conduction law.invention chemistry Chemical engineering law Specific surface area Electrochemistry Calcination Lithium Particle size
Zdroj:	Russian Journal of Electrochemistry. 57:499-504
ISSN:	1608-3342 1023-1935
Popis:	Lithium cobaltate with stoichiometric composition (LiCoO2) is synthesized by the sol–gel method. The physical parameters (particle size, specific surface area, and specific static conductivity) of studied samples are found and their dependence on the calcination temperature is revealed. The following three conduction mechanisms are shown to contribute to the conductivity value: frequency-independent σ0, ionic transport in the sample bulk σsv, and ionic transport at the electrode/ionic conductor interface σdl. The optimal modes of thermal treatment that allow the highly developed specific surface of LiCoO2 to be retained are determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4b80cc4e38ac38606e1ec48761501661 https://doi.org/10.1134/s1023193521050074 Zobrazit plný text záznamu Full text from SpringerLink