Carboxylate-substituted Ti(IV) oxo clusters with a Ti3O core

Autor:	Matthias Czakler, Ulrich S. Schubert
Rok vydání:	2018
Předmět:	Inorganic Chemistry chemistry.chemical_compound 010405 organic chemistry Chemistry Materials Chemistry Triphenylacetic acid Chelation Carboxylate Physical and Theoretical Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences
Zdroj:	Inorganica Chimica Acta. 471:567-569
ISSN:	0020-1693
DOI:	10.1016/j.ica.2017.11.055
Popis:	Ti3O(OiPr)6(OOC-adamantyl)4 and Ti3O2(OiPr)3(OOCCPh3)5 were obtained from the reaction of Ti(OiPr)4 with adamantylcarboxylic or triphenylacetic acid, respectively. The structures of both are based on a central Ti3O unit, which is substituted by different numbers of bridging carboxylate ligands and, in the case of the adamantyl derivative, also a chelating one.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4b80065fdebf037742ee8f87f50a3673 https://doi.org/10.1016/j.ica.2017.11.055 Zobrazit plný text záznamu Full Text from ScienceDirect