Determination of Abraham model solute descriptors for xanthone based on experimental solubility measurements at 298.2 K
| Autor: | William E. Acree, David Yue, Rachel Fischer, Melanie Che, Michael H. Abraham, Reese Neal, Ellen Qian, Grace Lee, Lainey Wang, Avi Gupta, Yuqing Liu, Megan Jodray |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
010304 chemical physics Methyl acetate Ethyl acetate 02 engineering and technology Condensed Matter Physics 01 natural sciences Electronic Optical and Magnetic Materials Propyl acetate chemistry.chemical_compound 020401 chemical engineering chemistry 0103 physical sciences Xanthone Materials Chemistry Physical chemistry Diisopropyl ether 0204 chemical engineering Physical and Theoretical Chemistry Solubility Butyl acetate Alkyl |
| Zdroj: | Physics and Chemistry of Liquids. 58:214-221 |
| ISSN: | 1029-0451 0031-9104 |
| DOI: | 10.1080/00319104.2019.1566462 |
| Popis: | Experimental solubilities have been determined for xanthone dissolved in 15 different alcohol solvents (ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, 1-heptanol, 1-octanol, 2-methyl-1-propanol, 3-methyl-1-butanol, 2-ethyl-1-hexanol, 2-propanol, 2-butanol, 4-methyl-2-pentanol, 2-methyl-2-propanol and 2-methyl-2-butanol), in five alkyl acetate solvents (methyl acetate, ethyl acetate, propyl acetate, butyl acetate and pentyl acetate), in diisopropyl ether and in 2-ethoxyethanol at 298.2 K. In total, solubility measurements were performed in 22 organic solvents of varying polarity and hydrogen-bonding character. Results of the experimental measurements were used to calculate the Abraham model solute descriptors for xanthone. The calculated solute descriptors describe the experimental solubility data to within 0.096 log units. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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