Molecular Organization of Alkoxy-Substituted Oligo(phenylene-ethynylene)s Studied by Scanning Tunneling Microscopy

Autor:	Li-Jun Wan, Shengbin Lei, and Xiao-Lin Fan, Chunli Bai, Zhishan Bo, Jian Ru Gong, Jing-Ling Zhao
Rok vydání:	2003
Předmět:	Steric effects Chemistry Hydrogen bond Intermolecular force Surfaces and Interfaces Conjugated system Condensed Matter Physics law.invention Crystallography law Monolayer Electrochemistry Alkoxy group Molecule General Materials Science Scanning tunneling microscope Spectroscopy
Zdroj:	Langmuir. 19:10128-10131
ISSN:	1520-5827 0743-7463
DOI:	10.1021/la034953x
Popis:	Morphologies and structures of self-assembled monolayers of two conjugated oligo(phenylene-ethynylene)s are observed by scanning tunneling microscopy at submolecular resolution. The cooperation of intermolecular and molecule/substrate interactions contributes to the long-range order. The influence of endgroups' hydrogen bonding and steric hindrance on the surface patterning is discussed. The different arrangement configuration of the two molecules could be due to the changed endgroups. This control of the two-dimensional self-assembly is promising for future studies on the electronic properties of these molecules.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4b16530e5e0ef0ccfd9bed90975dafa7 https://doi.org/10.1021/la034953x Zobrazit plný text záznamu