On the structural units in titanium-containing glasses and their influence on the opacity of glass coatings
Autor: | Ya. I. Belyi, A. V. Zaichuk, N. A. Minakova |
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Rok vydání: | 2008 |
Předmět: |
Materials science
Structure formation Opacity Enamel paint Oxide chemistry.chemical_element Mineralogy Condensed Matter Physics Alkali metal law.invention chemistry.chemical_compound chemistry Chemical engineering law visual_art Materials Chemistry Ceramics and Composites visual_art.visual_art_medium Crystallization Chemical composition Titanium |
Zdroj: | Glass Physics and Chemistry. 34:282-291 |
ISSN: | 1608-313X 1087-6596 |
DOI: | 10.1134/s1087659608030085 |
Popis: | A probable order of the formation of structural units in glasses of the Na2O-B2O3-SiO2, Na2O-TiO2-SiO2, and Na2O-B2O3-SiO2-TiO2 systems as a function of the alkali oxide content is analyzed in terms of the strengths of the cation-oxygen bonds of the glass components. The principle of the structure formation in silicate glasses is proposed. It is demonstrated that the chemical composition of glasses can be used to predict the existence of structural groups favoring the crystallization of titanium-containing phases in the glass and, consequently, the influence of the composition on the opacity of enamel coatings. |
Databáze: | OpenAIRE |
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