Additional diterpene ketones from Hypoestes forskalei
| Autor: | Farouk S. El-Feraly, Ilias Muhammad, Jaber S. Mossa, Ahmed F. Ramadan, Charles D. Hufford |
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| Rok vydání: | 1998 |
| Předmět: |
chemistry.chemical_classification
Ketone biology Stereochemistry Hypoestes Plant Science General Medicine Horticulture Carbon-13 NMR biology.organism_classification Biochemistry chemistry.chemical_compound chemistry Molecule Organic chemistry Diterpene Molecular Biology Two-dimensional nuclear magnetic resonance spectroscopy Derivative (chemistry) |
| Zdroj: | Phytochemistry. 47:1331-1336 |
| ISSN: | 0031-9422 |
| Popis: | The aerial parts of Hypoestes forskalei yielded three new fusicoccane diterpene ketones, named deoxyhypoestenone, dehydrohypoestenone and hypoestene. The structure and relative stereochemistry of the diterpenes were based on 1 H and 13 C NMR data, mainly 2D NMR experiments, including 1 H 1 H long range COSY, 1 H 13 C long range HETCOR and 1 H 1 H NOESY correlations, as well as chemical derivation of deoxyhypoestenone to its corresponding 8(9)α-epoxy derivative. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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