The synthesis and reactions of β-substituted ethyl sulfates

Autor: John Carl Falk, Donald A. Tomalia
Rok vydání: 1972
Předmět:
Zdroj: Journal of Heterocyclic Chemistry. 9:891-894
ISSN: 1943-5193
0022-152X
DOI: 10.1002/jhet.5570090424
Popis: The synthesis of β-substituted ethyl sulfates and their reactions with nucleophilic reagents has been studied. Amines, phenolates, carboxylates, amine oxides, carbanions, and thiophenolates reacted with ethylene sulfate in high yield, with short reaction times, and at low temperatures, to form β-substituted ethyl sulfates. The β-substituted ethyl sulfates were easily hydrolyzed and in some cases were converted into polymeric material.
Databáze: OpenAIRE