Oxidation of iron powders

Autor: G. I. Aksenov, Yu. P. Orekhov, V. K. Boikov
Rok vydání: 1974
Předmět:
Zdroj: Soviet Powder Metallurgy and Metal Ceramics. 13:185-188
ISSN: 0038-5735
DOI: 10.1007/bf00790631
Popis: 1. It is shown that with rise in temperature and increase in exposure time, water vapor concentration in the atmosphere, and particle size the rate of oxidation of an iron powder grows. On the basis of experimental data, formulas have been derived enabling the relative weight gain of a powder and the thickness of magnetite films on its particles to be determined as functions of the above factors. 2. Comparison of weight gains due to oxidation in water vapor, calculated with the familiar formula for bulk iron, and weight gains determined experimentally for an iron powder indicates that the formula does not express the oxidation characteristics of a powder. Good agreement with experimental values is given by weight gains obtained with a formula taking into account also the powder particle size and the amount of oxidizing components in the atmosphere. 3. Results of x-ray structural analysis have shown that the oxidation of an iron powder results in the formation of magnetite at temperatures of 350 and 450‡C and of wustite and magnetite at 550‡C.
Databáze: OpenAIRE