Determination of the standard molar Gibbs energy of formation of calcium zirconate by a galvanic cell involving calcium-ion conducting solid electrolyte
Autor: | G. Róg, M. Potoczek-Dudek |
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Rok vydání: | 2001 |
Předmět: |
Electromotive force
Standard molar entropy Chemistry Inorganic chemistry Enthalpy Analytical chemistry Electrolyte Atmospheric temperature range Atomic and Molecular Physics and Optics Standard enthalpy of formation Gibbs free energy symbols.namesake symbols Galvanic cell General Materials Science Physical and Theoretical Chemistry |
Zdroj: | The Journal of Chemical Thermodynamics. 33:77-82 |
ISSN: | 0021-9614 |
DOI: | 10.1006/jcht.2000.0722 |
Popis: | The standard molar Gibbs energy of formation of CaZrO3from CaO andZrO2 has been determined by the e.m.f. measurements of a galvanic cell with calcium-ion conducting solid-state electrolyte in the temperature range 1073 K to 1273 K. The average values of the standard enthalpy and the standard entropy in the temperature range covered by the e.m.f. measurements have also been estimated. The results have been compared with those obtained by other authors. |
Databáze: | OpenAIRE |
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