Combined Metalation–Cross Coupling Strategies: A Synthesis of Schumanniophytine by a Key BiarylO-Carbamate Remote Anionic Fries Rearrangement

Autor:	Victor Snieckus, Todd Macklin, Mark A. Reed
Rok vydání:	2008
Předmět:	Carbamate Chemistry Fries rearrangement Stereochemistry Metalation medicine.medical_treatment Organic Chemistry medicine Physical and Theoretical Chemistry Directed ortho metalation
Zdroj:	European Journal of Organic Chemistry. 2008:1507-1509
ISSN:	1099-0690 1434-193X
DOI:	10.1002/ejoc.200701116
Popis:	A short synthesis of the alkaloid schumanniophytine (1) starting from simple building blocks and involving directed ortho metalation (DoM), Suzuki–Miyaura cross coupling, and a key ortho-silicon-induced O-carbamate remote anionic Fries rearrangement (3) is described. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
Databáze:	OpenAIRE
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