Intermolecular magnetic exchange interactions in structural polytypes of iodobis(morpholyldithiocarbamate)iron (III)

Autor: H. H. Wickman, G. L. Robbins, J.M. Grow
Rok vydání: 1976
Předmět:
Zdroj: Chemical Physics Letters. 43:77-80
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80760-9
Popis: The title complex exhibits a number of allotropes or solvent adducts, several of which show cooperative magnetic transitions in the helium temperature range. These materials represent a useful class of metal complexes in which intermolecular magnetic exchange between identical molecules in variable lattice orientations may be studied. Low temperature Mossbauer hfs properties of four species are reported here; this information is used to determine the crystal field splitting within the ground quartet state of the complex.
Databáze: OpenAIRE