Synthesis of 1,2,3-Triazolo[1,5-а]Pyridin-8-Ium-3-Olates

Autor:	Julia I. Nein, Pavel M. Demkin, Yuri Yu. Morzherin, Tatiana V. Glukhareva, Inna S. Khazhieva
Rok vydání:	2015
Předmět:	chemistry Stereochemistry Sodium Intramolecular force Organic Chemistry Condensation chemistry.chemical_element Alkylation Medicinal chemistry
Zdroj:	Chemistry of Heterocyclic Compounds. 51:199-202
ISSN:	1573-8353 0009-3122
DOI:	10.1007/s10593-015-1681-x
Popis:	Alkylation of sodium 4-acetyl-1-phenyl-1,2,3-triazol-5-olate with α-bromoacetophenones was shown to occur at position 3 of the heterocycle, with the formation of 1,2,3-triazol-3-ium-5-olates. Intramolecular crotonic condensation of the latter led to the formation of 1,2,3-triazolo[1,5-а]pyridin-8-ium-3-olates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4a3278f5c52eb61d7a3ceed312ad3edd https://doi.org/10.1007/s10593-015-1681-x Zobrazit plný text záznamu Plný text ve formátu PDF