Solvent effects on the free-radical copolymerization of styrene with butyl acrylate. I. Monomer reactivity ratios

Autor:	Marta Fernández-García, M. C. Fernández-Monreal, Marina Fernández-Sanz, Vicente Hernández-Gordo, Rocío Cuervo-Rodríguez, Enrique López Madruga
Rok vydání:	2000
Předmět:	Polymers and Plastics Butyl acrylate Organic Chemistry Styrene chemistry.chemical_compound Benzonitrile Monomer chemistry Polymer chemistry Materials Chemistry Copolymer Reactivity (chemistry) Solvent effects Benzene
Zdroj:	Journal of Polymer Science Part A: Polymer Chemistry. 38:60-67
ISSN:	1099-0518 0887-624X
DOI:	10.1002/(sici)1099-0518(20000101)38:1<60::aid-pola8>3.0.co;2-f
Popis:	The free-radical copolymerization of styrene with butyl acrylate was carried out in benzene and benzonitrile at 50°C. Differences between the apparent reactivity ratios determined in this work and those previously reported in bulk indicated noticeable solvent effects. This is explained by a qualitative bootstrap effect. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 60–67, 2000
Databáze:	OpenAIRE
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