A cautionary comment on a recent communication entitled 'A measure of charge transfer (ϱ) versus a measure of bond tightness (ϱij) in the transition state'

Autor:	J.P. King, S. Skonieczny
Rok vydání:	1987
Předmět:	Stereochemistry Bond Organic Chemistry Charge (physics) State (functional analysis) Biochemistry Measure (mathematics) Interpretation (model theory) chemistry.chemical_compound Transfer (group theory) chemistry Quantum mechanics Sulfene Drug Discovery Tetrahedron
Zdroj:	Tetrahedron Letters. 28:5001-5004
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)96680-2
Popis:	We present evidence that the reaction of anilines with ArCH2SO2Cl and ArCH2SO2F goes mainly via the sulfene (ArCHSO2) and is not a simple nucleophilic displacement at sulfur, as was assumed in the above paper by I. Lee and R.K. Kang (Tetrahedron Lett. 28, 1183 (1987)), and hence that their conclusions about the interpretation of ϱ and ϱXY values are unfounded.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4a25c5e235c39d5de53eff4ad3a9e712 https://doi.org/10.1016/s0040-4039(00)96680-2 Zobrazit plný text záznamu