Gold and silver complexes of methylenebis(dialkyldithiocarbamates) and the X-ray structure of CH2[S2CN(CH2Ph)2]2

Autor:	Henry H. Murray, Antonio Laguna, Eduardo Jambrina, M. Concepción Gimeno, Raquel Terroba, Mariano Laguna
Rok vydání:	1996
Předmět:	chemistry.chemical_classification Chemistry Cationic polymerization X-ray Crystal structure Conductivity Coordination complex Inorganic Chemistry Crystallography Elemental analysis Materials Chemistry Mass spectrum Physical and Theoretical Chemistry Single crystal
Zdroj:	Inorganica Chimica Acta. 249:69-77
ISSN:	0020-1693
DOI:	10.1016/0020-1693(96)05027-x
Popis:	The coordination chemistry of CH2(S2CNR2)2 for R = Me, Et, n-Bu and benzyl with Au(I), Au(III) and Ag(I) is examined. The single crystal X-ray diffraction study of CH2[S2CN(CH2Ph)2]2 is described. Nineteen new complexes are characterized by IR, 1H, 19F, 31P (when appropriate) NMR, elemental analysis, mass spectra (FAB) and conductivity measurements. Neutral and cationic mono- and dinuclear species have been synthesized. The coordination chemistry of CH2(S2CNR2)2 is via the CS functionality.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4a22ef27c1e077fe84e984ff2fc50393 https://doi.org/10.1016/0020-1693(96)05027-x Zobrazit plný text záznamu Full Text from ScienceDirect