Infrared photochemical properties of sensitized SO2O2 mixtures

Autor:	Ion N. Voicu, N. Chitica, I.N. Mihailescu, R. Alexandrescu, Dan C. Dumitras, I. Morjan
Rok vydání:	1996
Předmět:	Range (particle radiation) Ternary numeral system Infrared General Chemical Engineering General Physics and Astronomy General Chemistry Photochemistry Sulfur hexafluoride chemistry.chemical_compound chemistry Torr Reactivity (chemistry) Irradiation Absorption (electromagnetic radiation)
Zdroj:	Journal of Photochemistry and Photobiology A: Chemistry. 93:89-95
ISSN:	1010-6030
DOI:	10.1016/1010-6030(95)04194-x
Popis:	Sulphur dioxide photo-oxidation in sensitized SO 2 O 2 mixtures at overall pressures of several hundred Torr was studied in the CO 2 laser emission range on addition of different absorbing gases (SF 6 , C 2 H 4 F 2 , C 2 HCl 3 ). The extent of conversion was correlated in each case with the absorption of energy by the specific ternary system under investigation. To explain the high reactivity found in SO 2 O 2 C 2 H 4 F 2 mixtures irradiated with the 9R24 laser line, the gas temperature inside the laser beam was estimated and a model of the energy transfer processes at different irradiation frequencies was proposed. It is suggested that, complementary to the thermalized chemistry, a vibrational enhancement of SO 2 oxidation can occur when the laser frequency correlates with the energy level structure of the specific molecular system employed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4a1feaf248bf6df6fd4c1241bc585165 https://doi.org/10.1016/1010-6030(95)04194-x Zobrazit plný text záznamu Full Text from ScienceDirect