Systems: MCl-AlCl3-Solv at 25�C (M=Na,K,Rb,Cs; Solv=diethyl ether and toluene)

Autor:	A. E. Pruntsev, S. M. Arkhipov, V. I. Mikheeva
Rok vydání:	1973
Předmět:	Inorganic chemistry chemistry.chemical_element Ether General Chemistry Alkali metal Chloride Toluene law.invention chemistry.chemical_compound chemistry law medicine Lithium Diethyl ether Crystallization Solubility medicine.drug
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 22:1148-1149
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00854280
Popis:	1. Employing the method of constructing the solubility isotherms, a study was made of the systems: MCl-AlCl3-Solv at 25°, where M=Na, K, Rb, Cs, and Solv=diethyl ether and toluene. 2. The NaCl-AlCl3-Et2O isotherm at 25° is characterized by two crystallization branches: NaCl and the solvate AlCl3·Et2O. 3. The MCl-AlCl3-Et2O isotherms at 25°, where M=K, Rb, Cs, have three crystallization branches: MCl, MAlCl4, and AlCl3-Et2O. 4. The equilibrium in the systems: MCl-AlCl3-C7H8 (M=Na, K, Rb, Cs) at 25° is determined by the successive crystallization of MCl, MAlCl4, and AlCl3. 5. For the systems: MCl-AlCl3-C7H8 a steady decrease in the solubility of the alkali metal chloride when going from lithium to cesium is characteristic when aluminum chloride is added.
Databáze:	OpenAIRE
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