Unexpected behavior of dienol thio ethers gives versatile access to a large set of functionalized dienes

Autor:	Lucette Duhamel, Odile Gaonac'h, Jacques Maddaluno, Joë Chauvin
Rok vydání:	1991
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Nucleophile Thioether Organic Chemistry Acetal Enol ether Thio Stereoselectivity Combinatorial chemistry
Zdroj:	The Journal of Organic Chemistry. 56:4045-4048
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo00012a045
Popis:	We present in this work: (i) the first stereoselective access to 4-methoxy-1-(phenylthio) buta-1,3-diene based on 1,4-elimination of corresponding thioether acetal 4, (ii) the exceptional ability of nucleophilic additions to take place on such substrates, giving easy access to a large set of functionalized dienes
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4a086ba8a62706722c919ab0947c0bef https://doi.org/10.1021/jo00012a045 Zobrazit plný text záznamu