The Determination of Enantiomeric Excess of the Products of Baker’s Yeast-mediated Reduction of d-Alkoxycarbonyl-b-keto Esters, via the Derivation to Alexakis’ Alkoxydiazaphosphoridine

Autor:	Magdalena Jaremko, Iwona Matuszewska, Jerzy Szychowski, Krystyna Wojtasiewicz, Jacek Nowacki, Zbigniew Czarnocki
Rok vydání:	2002
Předmět:	Pharmacology Reduction (complexity) Stereochemistry Chemistry Organic Chemistry Enantioselective synthesis Organic chemistry Enantiomeric excess Yeast Analytical Chemistry
Zdroj:	HETEROCYCLES. 57:705
ISSN:	0385-5414
Popis:	Reduction of 5-alkoxycarbonyl-3-oxopentanoates (la-lj) with baker's yeast turned to be enantioselective, and the e.es of the products (2a-2j) were determined by the NMR measurement of the corresponding Alexakis' alkoxydiazaphosphoridines. Stereochemistry was established with X-Ray crystallography.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::49fccc6684ca3425289371394b2b1a18 https://doi.org/10.3987/com-01-9403 Zobrazit plný text záznamu