ChemInform Abstract: Chiral-Anion-Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium-Catalyzed Butadiene Hydrohydroxyalkylation

Autor:	Emma L. McInturff, Michael J. Krische, Eiji Yamaguchi
Rok vydání:	2013
Předmět:	chemistry.chemical_compound chemistry Polymer chemistry chemistry.chemical_element Ruthenium catalyst General Medicine Inversion (discrete mathematics) Phosphoric acid Ion Catalysis Ruthenium
Zdroj:	ChemInform. 44
ISSN:	0931-7597
DOI:	10.1002/chin.201322047
Popis:	The ruthenium catalyst generated in situ from H2Ru(CO)(PPh3)3, (S)-SEGPHOS, and a TADDOL-derived phosphoric acid (TPA) promotes butadiene hydrohydroxyalkylation to form enantiomerically enriched products.
Databáze:	OpenAIRE
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