One-dimensional Hydrogen-bonded Chloride-Hydrate Assembly {[(H2O)4Cl2]2–}∞

Autor:	Qian-Feng Zhang, Wen-Rui Yao, Fang-Hui Wu, Ji-Xiang Dai
Rok vydání:	2007
Předmět:	Hydrogen chemistry Hydrogen bond Polymer chemistry medicine Supramolecular chemistry chemistry.chemical_element General Chemistry Self-assembly Hydrate Chloride medicine.drug
Zdroj:	Zeitschrift für Naturforschung B. 62:491-494
ISSN:	1865-7117 0932-0776
DOI:	10.1515/znb-2007-0401
Popis:	A hydrogen-bonded chloride-hydrate assembly {[(H2O)4Cl2]2−}∞ has been ion-countered by the complex cations [Fe([9]aneS3)2]2+ ([9]aneS3 = 1,4,7-trithiacyclononane). In {[(H2O)4Cl2]2−}∞, four water molecules and two chloride ions are self-assembled to form a one-dimensional supramolecular array of O-H···O and O-H···Cl hydrogen bonding, which consists of fused fourand six-membered rings. The discrete cation [Fe([9]aneS3)2]2+ has a nearly regular octahedral FeS6 core with an average Fe-S bond length of 2.2586(5) Å .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::49afa3b1c2d18e806d81e68932aacf4f https://doi.org/10.1515/znb-2007-0401 Zobrazit plný text záznamu