Thermal and photolytic decomposition of alkoxy-lead(IV)-acetates derived from saturated aliphatic alcohols

Autor:	Ž. Čeković, M.Lj. Mihallović, M. Jakovjević
Rok vydání:	1969
Předmět:	Organic Chemistry Biochemistry Medicinal chemistry Decomposition chemistry.chemical_compound chemistry Intramolecular force Drug Discovery Thermal Alkoxy group Organic chemistry Thermal reaction Irradiation Benzene
Zdroj:	Tetrahedron. 25:2269-2273
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(01)82776-9
Popis:	Intramolecular formation of tetrahydrofuran-type ethers from saturated aliphatic alcohols and lead tetraacetate can be readily achieved at room temperature by UV irradiation of the reaction mixture in benzene. The yields of cyclic ethers and β-fragmentation products (when formed) are comparable to or even somewhat higher (under suitable conditions) than those observed in the thermal reaction, whereas the formation of carbonyl compounds (corresponding to the starting alcohols) is nearly completely suppressed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::49ad9b8981051761d02c9513dc432b15 https://doi.org/10.1016/s0040-4020(01)82776-9 Zobrazit plný text záznamu