Hydrogenation of carbon dioxide over copper-pyrochlore/zeolite composite catalysts

Autor:	Hisanori Ando, L. Udron, R. Kieffer, Masahiro Fujiwara, Yoshie Souma
Rok vydání:	1996
Předmět:	chemistry.chemical_classification Methanol reformer Chemistry Catalyst support Composite number Inorganic chemistry Industrial catalysts General Chemistry Catalysis chemistry.chemical_compound Hydrocarbon Methanol Zeolite
Zdroj:	Catalysis Today. 29:343-348
ISSN:	0920-5861
DOI:	10.1016/0920-5861(95)00302-9
Popis:	The hydrogenation of CO2 was studied over composite catalysts obtained by mixing Cu-based methanol synthesis catalyst and HY zeolite. A mechanism associating methanol synthesis and MTG (methanol to gasoline) reaction allowed the formation of C1-C4 hydrocarbons. It was found that the catalytic behaviors of the composite catalysts were favorably influenced by the characteristics of the methanol synthesis catalysts. The Cu-La2Zr2O7 catalyst we recently developed associated with HY zeolite exhibited interesting performances in hydrocarbon synthesis. The addition of ZrO2 to CuLa2Zr2O7/HY enhanced the ability to produce hydrocarbons. Comparing composite catalyst systems prepared with different Cu-based methanol synthesis catalysts, the effect of Na contamination on methanol and hydrocarbon formation over composite catalysts were also discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::49aaf369b8ab2e214993483cb4cab24c https://doi.org/10.1016/0920-5861(95)00302-9 Zobrazit plný text záznamu Full Text from ScienceDirect