2,6,8,12-Tetraoxa-4,10(1,4)-dibenzena-1,7(2,7)-difluorenacyclododecaphane-19,79-dione—A new macrocyclic receptor for polar organic molecules

Autor:	V. N. Pastushok, M. S. Fonar, N. G. Luk'yanenko, Yu. A. Simonov, A. Yu. Lyapunov, M. M. Botoshanskii, T. Yu. Bogashchenko
Rok vydání:	2006
Předmět:	Nitrobenzene Potassium carbonate chemistry.chemical_compound chemistry Molecular model Ligand Organic Chemistry Polymer chemistry Anhydrous Polar Substrate (chemistry) Benzene
Zdroj:	Russian Journal of Organic Chemistry. 42:1075-1082
ISSN:	1608-3393 1070-4280
Popis:	The results of computer-assisted molecular modeling showed that 2,6,8,12-tetraoxa-4,10(1,4)-dibenzena-1,7(2,7)-difluorenacyclododecaphane-19,79-dione is promising as a receptor for polar organic molecules. This compound was synthesized by the reaction of 1,4-bis(bromomethyl)benzene with 2,7-dihydroxyfluoren-9-one in DMF in the presence of anhydrous potassium carbonate under strong dilution. Crystalline complexes of the title compound with DMF and nitrobenzene were isolated and studied by X-ray diffraction. In both complexes the substrate is located in the ligand cavity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::497fb6fd1a08073c770b1386de93874c https://doi.org/10.1134/s1070428006070268 Zobrazit plný text záznamu Plný text ve formátu PDF